Ferrocene-driven single-chain polymer compaction

We introduce single-chain nanoparticles (SCNPs) exclusively folded by covalently bonded ferrocene units. Specifially, we demonstrate the ability of 2-ferrocenyl-1,10-phenanthroline to fuse single-chain collapse with the concomitant introduction of a donor functionality allowing the installation of a...

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Published inChemical communications (Cambridge, England) Vol. 59; no. 31; pp. 4672 - 4675
Main Authors Gillhuber, Sebastian, Holloway, Joshua O, Frisch, Hendrik, Feist, Florian, Weigend, Florian, Barner-Kowollik, Christopher, Roesky, Peter W
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 13.04.2023
Subjects
Nanoparticles
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Summary:We introduce single-chain nanoparticles (SCNPs) exclusively folded by covalently bonded ferrocene units. Specifially, we demonstrate the ability of 2-ferrocenyl-1,10-phenanthroline to fuse single-chain collapse with the concomitant introduction of a donor functionality allowing the installation of a Pd-catalytic site, affording the first heterobimetallic ferrocene-functionalized SCNP. We introduce single-chain nanoparticles (SCNPs) whose folding is driven by ferrocene units while concomitantly carrying catalytically active species, establishing a bimetallic SCNP system that pushes the contemporary limits of SCNP design.
Bibliography:https://doi.org/10.1039/d3cc00736g
Electronic supplementary information (ESI) available. See DOI
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/d3cc00736g