Control of the photodissociation process of CsCl using a feedback-controlled self-learning fs-laser system
The time-resolved photoinduced dissociation process of a diatomic molecule (CsCl) was investigated both theoretically and experimentally. It is shown that by applying a sequence of two different laser pulses the dissociation process may be controlled, according to the Tannor–Rice scheme. Using feedb...
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Published in | Chemical physics Vol. 267; no. 1; pp. 223 - 229 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
01.06.2001
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Subjects | |
Online Access | Get full text |
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Summary: | The time-resolved photoinduced dissociation process of a diatomic molecule (CsCl) was investigated both theoretically and experimentally. It is shown that by applying a sequence of two different laser pulses the dissociation process may be controlled, according to the Tannor–Rice scheme. Using feedback-controlled optimization algorithms a self-learning system has been realized, which is able to control the product channel without a priori knowledge on the molecular potential surfaces. |
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ISSN: | 0301-0104 |
DOI: | 10.1016/S0301-0104(01)00257-9 |