Heteroepitaxy and nitrogen doping of high-quality ZnO

• Published in: Journal of crystal growth Vol. 272; no. 1; pp. 800 - 804
• Main Authors: Dadgar, A., Oleynik, N., Bläsing, J., Deiter, S., Forster, D., Bertram, F., Diez, A., Seip, M., Greiling, A., Christen, J., Krost, A.
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Amsterdam Elsevier B.V 10.12.2004; Elsevier
• Subjects: A1. doping; A3. metalorganic vapour-phase epitaxy; B1. oxides; B1. Zinc compounds; B2. semiconducting II–VI materials; Cathodoluminescence, ionoluminescence; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Defects and impurities: doping, implantation, distribution, concentration, etc; Exact sciences and technology; Materials science; Methods of deposition of films and coatings; film growth and epitaxy; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation; Other luminescence and radiative recombination; Physics; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties); Thin film structure and morphology; Vapor phase epitaxy; growth from vapor phase; 78.55.Et; 61.10.Nz; 71.55.Gs; A3. metalorganic vapour-phase epitaxy; 73.61.Ga; B2. semiconducting II–VI materials; 81.15.Gh; B1. Zinc compounds; A1. doping; B1. oxides; Inorganic compounds; Doping; VPE; Crystal growth from vapors; Cathodoluminescence; CV characteristic; Thin films; Nitrogen additions; Annealing; B2. semiconducting II-VI materials; Transition element compounds; Binary compounds; Experimental study; 71.55.Gs Al. doping; Zinc oxides; Quantity ratio; Acceptor center; II-VI semiconductors; MOVPE method; Heteroepitaxy; Carrier density
• ISSN: 0022-0248; 1873-5002
• DOI: 10.1016/j.jcrysgro.2004.08.030

We present a two-step growth process for ZnO on GaN templates to achieve high-quality ZnO layers with XRD rocking curve FWHMs of the (0 0 0 2) reflection of ∼180″ and narrow cathodoluminescence of 1.3 meV of the dominant I8 emission. These layers are applied for an investigation of potential nitrogen doping sources to achieve p-type doping of ZnO, namely NH 3, UDMHy, and NO. Of these sources NO seems to induce only little changes in the optical and electrical properties of the material. A brownish colour of the samples is observed when using NH 3 or UDMHy at higher dopant flows. With it we find an increase in the electron carrier concentration from 10 16 cm −3 to above 10 18 cm −3. For some samples grown with lower dopant flows, we observe a decrease in the carrier concentration upon annealing to values significantly lower than the background doping concentration when using UDMHy. The sample which shows the strongest decrease in the carrier concentration also shows a pronounced DAP emission which vanishes upon annealing, most likely due to activation of an acceptor state.