A New Method for the Synthesis of Aromatic Sulfurpentafluorides and Studies of the Stability of the Sulfurpentafluoride Group in Common Synthetic Transformations

A new synthesis of aromatic sulfurpentafluoride compounds is described. Subsequent elaboration of the aromatic rings in the presence of the sulfurpentafluoride group is also discussed for a variety of common synthetic methods. This paper also describes ab initio electronic structure calculations of...

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Bibliographic Details
Published inTetrahedron Vol. 56; no. 21; pp. 3399 - 3408
Main Authors Bowden, Roy D, Comina, Paul J, Greenhall, Martin P, Kariuki, Benson M, Loveday, Amanda, Philp, Douglas
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 19.05.2000
Elsevier
Subjects
Chemistry
Chemistry, Organic
coupling reactions
fluorine and compounds
Physical Sciences
Science & Technology
sulfur halogen compounds
X-ray crystallography
X-ray crystallography
sulfur halogen compounds
coupling reactions
fluorine and compounds
HALIDES
SUBSTITUENTS
SOLID-STATE STRUCTURES
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Summary:A new synthesis of aromatic sulfurpentafluoride compounds is described. Subsequent elaboration of the aromatic rings in the presence of the sulfurpentafluoride group is also discussed for a variety of common synthetic methods. This paper also describes ab initio electronic structure calculations of 3- and 4-aminophenylsulfurpentafluoride, compared with 3- and 4-aminobenzotrifluoride, and presents X-ray crystal structures of two aromatic sulfurpentafluoride derivatives.
ISSN:0040-4020
1464-5416
DOI:10.1016/S0040-4020(00)00184-8