Synthesis of homochiral cyclopentane derivatives by Beckmann fragmentation of 1-substituted 2-norbornanones

The fragmentation of 2-norbornanone oximes 2 was achieved by reaction with Tf 2O/pyridine under mild reaction conditions, yielding homochiral (or racemic) cyclopentane derivativel. Graphic

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Bibliographic Details
Published inTetrahedron: asymmetry Vol. 5; no. 5; pp. 949 - 954
Main Authors Martínez, A.García, Vilar, E.Teso, García Fraile, A., de la Moya Cerero, S., Oliva, C.Díaz, Subramanian, L.R., Maichle, C.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 01.05.1994
Elsevier
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Chemistry, Physical
Physical Sciences
Science & Technology
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Summary:The fragmentation of 2-norbornanone oximes 2 was achieved by reaction with Tf 2O/pyridine under mild reaction conditions, yielding homochiral (or racemic) cyclopentane derivativel. Graphic
ISSN:0957-4166
1362-511X
DOI:10.1016/S0957-4166(00)86247-3