Recent evidence for a strengthening CO2 sink in the Southern Ocean from carbonate system measurements in the Drake Passage (2002-2015)

• Published in: Geophysical research letters Vol. 42; no. 18; pp. 7623 - 7630
• Main Authors: Munro, David R., Lovenduski, Nicole S., Takahashi, Taro, Stephens, Britton B., Newberger, Timothy, Sweeney, Colm
• Format: Journal Article
• Language: English
• Published: Washington Blackwell Publishing Ltd 28.09.2015; John Wiley & Sons, Inc
• Subjects: Antarctic convergence; Antarctic front; Aragonite; carbon cycling; Carbon dioxide; Carbonates; Cooling; Meteorology; Ocean currents; Oceans; Parameters; Partial pressure; Polar fronts; Pressure; Sea surface; Sea surface temperature; Southern Ocean; Stability; Summer; Surface stability; Surface temperature; Surface water; Temperature (air-sea); Time series; Trends; Uptake; Winter; Drake Passage; Southern Ocean
• ISSN: 0094-8276; 1944-8007
• DOI: 10.1002/2015GL065194

We present a 13 year (2002–2015) semimonthly time series of the partial pressure of CO2 in surface water (pCO2surf) and other carbonate system parameters from the Drake Passage. This record shows a clear increase in the magnitude of the sea‐air pCO2 gradient, indicating strengthening of the CO2 sink in agreement with recent large‐scale analyses of the world oceans. The rate of increase in pCO2surf north of the Antarctic Polar Front (APF) is similar to the atmospheric pCO2 (pCO2atm) trend, whereas the pCO2surf increase south of the APF is slower than the pCO2atm trend. The high‐frequency surface observations indicate that an absence of a winter increase in total CO2 (TCO2) and cooling summer sea surface temperatures are largely responsible for increasing CO2 uptake south of the APF. Muted winter trends in surface TCO2 also provide temporary stability to the carbonate system that is already close to undersaturation with respect to aragonite. Key Points Ocean pCO2 increasing more slowly than atmospheric pCO2 south of the Antarctic Polar Front Lack of winter TCO2 increase and cooling summer sea surface temperatures drive ocean pCO2 trends Lack of winter TCO2 increase causes temporary winter stability in carbonate ion concentration