Self‐Forming Interlocking Interfaces on the Immiscible Polymer Bilayers via Gelation‐Mediated Phase Separation
Gelation‐mediated phase separation is applied to prepare immiscible polymer bilayer films with an interlocking interface structure. Polymer systems consisting of copolymer of urea and polydimethylsiloxane and epoxy are selected to demonstrate the feasibility. When the epoxy fraction exceeds 25 wt%,...
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Published in | Macromolecular rapid communications. Vol. 38; no. 17 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Germany
Wiley Subscription Services, Inc
01.09.2017
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Subjects | |
Online Access | Get full text |
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Summary: | Gelation‐mediated phase separation is applied to prepare immiscible polymer bilayer films with an interlocking interface structure. Polymer systems consisting of copolymer of urea and polydimethylsiloxane and epoxy are selected to demonstrate the feasibility. When the epoxy fraction exceeds 25 wt%, well‐defined bilayer structures self‐form by a one‐pot casting method in which the phase separation state is fixed by an evaporation‐induced gelation. Microscopy studies of the resulting bilayers clearly reveal that interlocking structures form during the bilayer films construct. The interlocking structures lead to an enhanced interfacial adhesion and higher fracture energy. The current strategy might offer a facile way to in situ create an interlocking interface between immiscible polymer systems.
Interlocking interface structure self‐forms between immiscible silicone/epoxy bilayers when evaporation‐induced gelation occurs during phase separation. At the phase separating interface, droplets are fixed when approaching their homogeneous phases. This facile one‐pot casting method can increase interface adhesion without changing interface chemical composition. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1022-1336 1521-3927 |
DOI: | 10.1002/marc.201700206 |