Heteroleptic Tripalladium(II) Cages

There is a concerted attempt to develop self‐assembled metallo‐cages of greater structural complexity, and heteroleptic PdII cages are emerging as prime candidates in these efforts. Most of these are dinuclear: few examples of higher nuclearity have been reported. We demonstrate here a robust method...

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Published inChemistry, an Asian journal Vol. 17; no. 6; pp. e202200093 - n/a
Main Authors Findlay, James A., Patil, Komal M., Gardiner, Michael G., MacDermott‐Opeskin, Hugo I., O'Mara, Megan L., Kruger, Paul E., Preston, Dan
Format Journal Article
LanguageEnglish
Published Germany Wiley Subscription Services, Inc 14.03.2022
Subjects
Cages
Chemistry
heteroleptic
Ligands
Metallography
metallosupramolecular
Palladium - chemistry
palladium(II)
self-assembly
metallosupramolecular
self-assembly
palladium(II)
cages
heteroleptic
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Summary:There is a concerted attempt to develop self‐assembled metallo‐cages of greater structural complexity, and heteroleptic PdII cages are emerging as prime candidates in these efforts. Most of these are dinuclear: few examples of higher nuclearity have been reported. We demonstrate here a robust method for the formation of tripalladium(II) cages from the 2 : 3 : 3 combination of a tritopic ligand, PdII, and a selection of ditopic ligands of the correct size and geometry. Heteroleptic [Pd3L2L’3]6+ cages have been formed from a tritopic ligand (L) and a range of ditopic ligands (L’).
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ISSN:1861-4728
1861-471X
DOI:10.1002/asia.202200093