Electrolyte Regulation of Bio‐Inspired Zincophilic Additive toward High‐Performance Dendrite‐Free Aqueous Zinc‐Ion Batteries

• Published in: Small (Weinheim an der Bergstrasse, Germany) Vol. 19; no. 10; pp. e2207502 - n/a
• Main Authors: Gou, Qianzhi, Luo, Haoran, Zhang, Qi, Deng, Jiangbin, Zhao, Ruizheng, Odunmbaku, Omololu, Wang, Lei, Li, Lingjie, Zheng, Yujie, Li, Jun, Chao, Dongliang, Li, Meng
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 01.03.2023
• Subjects: Additives; Amino acids; Aqueous electrolytes; aqueous zinc‐ion batteries; bio‐inspired design; dendrite growth; Electrochemical analysis; Electrolytes; Electrolytic cells; Energy storage; Glycine; glycine additive; Manganese dioxide; Nanotechnology; Sheaths; Solvation; Zinc; zincophilicity; dendrite growth; aqueous zinc-ion batteries; bio-inspired design; glycine additive; zincophilicity
• ISSN: 1613-6810; 1613-6829
• DOI: 10.1002/smll.202207502

Aqueous zinc‐ion batteries hold attractive potential for large‐scale energy storage devices owing to their prominent electrochemical performance and high security. Nevertheless, the applications of aqueous electrolytes have generated various challenges, including uncontrolled dendrite growth and parasitic reactions, thereby deteriorating the Zn anode's stability. Herein, inspired by the superior affinity between Zn2+ and amino acid chains in the zinc finger protein, a cost‐effective and green glycine additive is incorporated into aqueous electrolytes to stabilize the Zn anode. As confirmed by experimental characterizations and theoretical calculations, the glycine additives can not only reorganize the solvation sheaths of hydrated Zn2+ via partial substitution of coordinated H2O but also preferentially adsorb onto the Zn anode, thereby significantly restraining dendrite growth and interfacial side reactions. Accordingly, the Zn anode could realize a long lifespan of over 2000 h and enhanced reversibility (98.8%) in the glycine‐containing electrolyte. Furthermore, the assembled Zn||α‐MnO2 full cells with glycine‐modified electrolyte also delivers substantial capacity retention (82.3% after 1000 cycles at 2 A g‐1), showing promising application prospects. This innovative bio‐inspired design concept would inject new vitality into the development of aqueous electrolytes. Inspired by the affinity between Zn2+ and amino acid chains in zinc finger protein, a glycine additive is incorporated to stabilize Zn anode. As confirmed by experimental characterizations and theoretical calculations, this additive can reorganize the solvation sheaths of hydrated Zn2+ via partial substitution of coordinated H2O and preferentially adsorb onto the Zn anode, thereby restraining dendrites and side reactions.