Benzoquinone‐Lubricated Intercalation in Manganese Oxide for High‐Capacity and High‐Rate Aqueous Aluminum‐Ion Battery

• Published in: Small (Weinheim an der Bergstrasse, Germany) Vol. 20; no. 26; pp. e2310722 - n/a
• Main Authors: Meng, Huan, Ran, Qing, Zhu, Mei‐Hua, Zhao, Qiang‐Zuo, Han, Gao‐Feng, Wang, Tong‐Hui, Wen, Zi, Lang, Xing‐You, Jiang, Qing
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 01.06.2024
• Subjects: Aluminum; Al‐ion batteries; aqueous batteries; Aqueous electrolytes; Benzoquinone; Cathodes; Electrode materials; Energy storage; Intercalation; Interlayers; Lithium batteries; Manganese dioxide; manganese oxide; Manganese oxides; organic/inorganic hybrid material; Redox reactions; Structural stability; manganese oxide; organic/inorganic hybrid material; aqueous batteries; Al‐ion batteries
• ISSN: 1613-6810; 1613-6829; 1613-6829
• DOI: 10.1002/smll.202310722

Aqueous aluminum‐ion batteries are attractive post‐lithium battery technologies for large‐scale energy storage in virtue of abundant and low‐cost Al metal anode offering ultrahigh capacity via a three‐electron redox reaction. However, state‐of‐the‐art cathode materials are of low practical capacity, poor rate capability, and inadequate cycle life, substantially impeding their practical use. Here layered manganese oxide that is pre‐intercalated with benzoquinone‐coordinated aluminum ions (BQ‐AlxMnO2) as a high‐performance cathode material of rechargeable aqueous aluminum‐ion batteries is reported. The coordination of benzoquinone with aluminum ions not only extends interlayer spacing of layered MnO2 framework but reduces the effective charge of trivalent aluminum ions to diminish their electrostatic interactions, substantially boosting intercalation/deintercalation kinetics of guest aluminum ions and improving structural reversibility and stability. When coupled with Zn50Al50 alloy anode in 2 m Al(OTf)3 aqueous electrolyte, the BQ‐AlxMnO2 exhibits superior rate capability and cycling stability. At 1 A g−1, the specific capacity of BQ‐AlxMnO2 reaches ≈300 mAh g−1 and retains ≈90% of the initial value for more than 800 cycles, along with the Coulombic efficiency of as high as ≈99%, outperforming the AlxMnO2 without BQ co‐incorporation. An organic–inorganic hybrid material of manganese oxide pre‐intercalated with benzoquinone‐coordinated aluminum ions is developed as a cathode material of an aqueous aluminum‐ion battery. Owing to the coordination of flexible benzoquinone with Al3+ ions to extend interlayer spacing and weaken the electrostatic field of Al3+, it exhibits reversible Al3+ intercalation/extraction behaviors, with high capacity and rate capability, and long‐term stability.