Translating the Optimized Durability of Co‐Based Anode Catalyst into Sustainable Anion Exchange Membrane Water Electrolysis

• Published in: Small (Weinheim an der Bergstrasse, Germany) Vol. 20; no. 27; pp. e2311052 - n/a
• Main Authors: Han, Sanghwi, Ryu, Jae Hyun, Lee, Won Bo, Ryu, Jaeyune, Yoon, Jeyong
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 01.07.2024
• Subjects: anion exchange membrane water electrolysis; Anion exchanging; Catalysts; Catalytic activity; Chemical synthesis; Cobalt; Degradation; Durability; Electrocatalysts; Electrolysis; Electroplating; Green hydrogen; Heat treatment; Membranes; Oxygen evolution reactions; oxygen vacancy; anion exchange membrane water electrolysis; cobalt; electrocatalysts; oxygen vacancy; durability
• ISSN: 1613-6810; 1613-6829; 1613-6829
• DOI: 10.1002/smll.202311052

Development of robust electrocatalysts for the oxygen evolution reaction (OER) underpins the efficient production of green hydrogen via anion exchange membrane water electrolysis (AEMWE). This study elucidates the factors contributing to the degradation of cobalt‐based (Co‐based) OER catalysts synthesized via electrodeposition, thus establishing strategic approaches to enhance their longevity. Systematic variations in the electroplating process and subsequent heat treatment reveal a delicate balance between catalytic activity and durability, substantiated by comprehensive electrochemical assessments and material analyses. Building upon these findings, the Co‐based anode is successfully optimized in the AEMWE single‐cell configuration, showcasing an average degradation rate of 0.07 mV h−1 over a continuous operation for 1500 h at a current density of 1 A cm−2. An efficient strategy for enhancing the durability of Co‐based oxygen evolution catalyst is proposed. Through meticulous control of the electroplating and subsequent heat treatment, the durability is successfully improved at the expense of the initial performance. The optimized anode demonstrates exceptional durability for 1500 h at a current density of 1 A cm−2 in an anion exchange water electrolysis single‐cell.