Heterogeneous Electrospinning Nanofiber Membranes with pH‐regulated Ion Gating for Tunable Osmotic Power Harvesting

• Published in: Angewandte Chemie International Edition Vol. 62; no. 1; pp. e202212120 - n/a
• Main Authors: Ling, Haoyang, Xin, Weiwen, Qian, Yongchao, He, Xiaofeng, Yang, Linsen, Chen, Weipeng, Wu, Yadong, Du, Huaqing, Liu, Yang, Kong, Xiang‐Yu, Jiang, Lei, Wen, Liping
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 02.01.2023
• Edition: International ed. in English
• Subjects: Biological activity; Carboxylic acids; Channel gating; Electrospinning; Energy; Energy conversion; Energy harvesting; Fluidics; Heterogeneous Nanofiber Membrane; Hydrogen-Ion Concentration; Ion channels; Ion Channels - chemistry; Ion Gating; Ion Transport; Membranes; Nanofibers; Nanofluids; Nanotechnology; Osmotic Energy Harvesting; pH effects; Tunable Energy Conversion; Water treatment; Electrospinning; Tunable Energy Conversion; Ion Gating; Heterogeneous Nanofiber Membrane; Osmotic Energy Harvesting
• ISSN: 1433-7851; 1521-3773
• DOI: 10.1002/anie.202212120

Biological ion channels existing in organisms are critical for many biological processes. Inspired by biological ion channels, the heterogeneous electrospinning nanofiber membranes (HENM) with functional ion channels are constructed by electrospinning technology. The HENM successfully realizes ion‐gating effects, which can be used for tunable energy conversions. Introduction of pyridine and carboxylic acid groups into the HENM plays an important role in generating unique and stable ion transport behaviors, in which gates become alternative states of open and close, responding to symmetric/asymmetric pH stimulations. Then we used the HENM to convert osmotic energy into electric energy which reach a maximum value up to 12.34 W m−2 and the output power density of HENM‐based system could be regulated by ion‐gating effects. The properties of the HENM provide widespread potentials in application of smart nanofluidic devices, energy conversion, and water treatment. Heterogeneous electrospinning nanofiber membranes (HENMs) were constructed by electrospinning technology. HENMs demonstrate the fundamental property of ion gating, thus offering an adjustable gating effect for tunable energy conversion. This work has widespread potential for the application of smart nanofluidic devices, energy conversion, and water treatment.