Mechanical properties of individual MgAl2O4 agglomerates and their effects on densification
The presence of agglomerates during nanopowder sintering can be problematic and can limit achievable final densities. Typically, the practical solution is to use high pressures to overcome agglomerate breakdown strengths to reach higher packing fractions. The strength of agglomerates is often diffic...
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Published in | Acta materialia Vol. 69; pp. 187 - 195 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Kidlington
Elsevier Ltd
01.05.2014
Elsevier |
Subjects | |
Online Access | Get full text |
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Summary: | The presence of agglomerates during nanopowder sintering can be problematic and can limit achievable final densities. Typically, the practical solution is to use high pressures to overcome agglomerate breakdown strengths to reach higher packing fractions. The strength of agglomerates is often difficult to determine and makes processing parameters challenging to optimize. In this work, we used in situ transmission electron microscopy nanoindentation experiments to assess the mechanical properties of individual MgAl2O4 agglomerates under constant indenter head displacement rates. Electron microscopy revealed highly porous agglomerates with pores on both the micron and nanometric length scales. Individual agglomerate strength, at fracture, was calculated from compression tests with deformation behavior correlating well with previously reported modeling results. Macroscopic powder properties were also investigated using green-pressed pellets consolidated at pressures up to 910MPa. The unexpectedly high strength is indicative of the role agglomerates play in MgAl2O4 nanopowder densification. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1359-6454 1873-2453 |
DOI: | 10.1016/j.actamat.2014.01.051 |