Transition-metal catalyzed enantioselective hydrofunctionalization of alkynes

[Display omitted] •Advances in transition-metal catalyzed enantioselective alkynes hydrofunctionalization reactions.•Conia-Ene reaction, Mori-Montgomery-Jamison reaction, Krische coupling reaction.•Synthesis of chiral alkenes with allylic stereocenters. A significant number of reactions regarding hy...

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Bibliographic Details
Published inTetrahedron letters Vol. 59; no. 23; pp. 2205 - 2213
Main Authors Zheng, Yin, Zi, Weiwei
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 06.06.2018
Subjects
Alkynes
Enantioselective synthesis
Homogeneous catalysis
Hydrofunctionalization
Transition-metal catalysis
Hydrofunctionalization
Enantioselective synthesis
Homogeneous catalysis
Transition-metal catalysis
Alkynes
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Summary:[Display omitted] •Advances in transition-metal catalyzed enantioselective alkynes hydrofunctionalization reactions.•Conia-Ene reaction, Mori-Montgomery-Jamison reaction, Krische coupling reaction.•Synthesis of chiral alkenes with allylic stereocenters. A significant number of reactions regarding hydrofunctionalization of alkynes have appeared in the literature over the years. This digest focus on the transition-metal catalyzed enantioselective alkyne hydrofunctionalization reactions. Based on the reaction mechanism, these reactions described herein are classified into three types. Strategies, substrate scope, along with mechanisms are highlighting.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2018.04.057