Direct benzylation and allylic alkylation in high-temperature water without added catalysts

In high-temperature water a series of benzyl and allylic alcohols reacted with 1,3-dicarbonyl compounds and activated aromatic compounds to give the alkylated products without added catalysts.

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Bibliographic Details
Published inTetrahedron letters Vol. 51; no. 14; pp. 1847 - 1851
Main Authors Hirashita, Tsunehisa, Kuwahara, Shō, Okochi, Sota, Tsuji, Makoto, Araki, Shuki
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 07.04.2010
Elsevier
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
ALCOHOLS
CHEMICAL-REACTIONS
ONE-POT SYNTHESIS
ORGANIC-REACTIONS
NUCLEOPHILIC-SUBSTITUTION
AQUEOUS-MEDIA
ALLYLATION
DECOMPOSITION
EFFICIENT
INDOLES
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Summary:In high-temperature water a series of benzyl and allylic alcohols reacted with 1,3-dicarbonyl compounds and activated aromatic compounds to give the alkylated products without added catalysts.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2010.01.112