Effects of solvent on Raman band intensities
The intensity of a Raman band of a solute is dependent on the refractive index of the solution. When instrumental effects are factored out, the intensity shows a general increase with refractive index, the dependence being linear in many of the systems studied. For the binary solutions examined ther...
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| Published in | Journal of molecular spectroscopy Vol. 4; no. 1; pp. 507 - 517 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Inc
1960
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| Online Access | Get full text |
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| Summary: | The intensity of a Raman band of a solute is dependent on the refractive index of the solution. When instrumental effects are factored out, the intensity shows a general increase with refractive index, the dependence being linear in many of the systems studied. For the binary solutions examined there is no marked difference between polarized and depolarized bands or between polar and nonpolar solvents. No explanation for this behavior is advanced, current theories appearing inadequate. |
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| ISSN: | 0022-2852 1096-083X |
| DOI: | 10.1016/0022-2852(60)90114-4 |