Films of hydrocarbon—stearic acid mixtures

The formation of monomolecular layers on a barium buffer hypophase and of built-up Y-films is described for various mixtures of stearic acid with n-octadecane, n-octacosane, and n-hexatriacontane. The thickness of the resulting mixed films is interpreted with reference to their structure. The existe...

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Bibliographic Details
Published inJournal of colloid science Vol. 5; no. 6; pp. 581 - 585
Main Authors Sobotka, Harry, Rosenberg, Shirley
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.01.1950
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Summary:The formation of monomolecular layers on a barium buffer hypophase and of built-up Y-films is described for various mixtures of stearic acid with n-octadecane, n-octacosane, and n-hexatriacontane. The thickness of the resulting mixed films is interpreted with reference to their structure. The existence of a limiting proportion of 1 molecule of hydrocarbon to 2 molecules of stearic acid is explained by the crystal structure of the films. The relationship between three-dimensional and two-dimensional molecular compounds containing aliphatic acids is discussed.
ISSN:0095-8522
DOI:10.1016/0095-8522(50)90049-3