Photoelectron spectroscopy of liquids: relationships between ionization energy and reduction potential
The standard (reduction) potential of a half-cell, E, and the photoelectric work function, W(ev), are related by W= E + 4.4. Empirical relationships between the gas-phase ionization energy and polarographic half-wave potentials are given a theoretical basis.
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Published in | Chemical physics letters Vol. 42; no. 1; pp. 97 - 98 |
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Main Author | |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
01.08.1976
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Online Access | Get full text |
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Summary: | The standard (reduction) potential of a half-cell, E, and the photoelectric work function,
W(ev), are related by
W=
E + 4.4. Empirical relationships between the gas-phase ionization energy and polarographic half-wave potentials are given a theoretical basis. |
---|---|
ISSN: | 0009-2614 1873-4448 |
DOI: | 10.1016/0009-2614(76)80559-3 |