Photoelectron spectroscopy of liquids: relationships between ionization energy and reduction potential

The standard (reduction) potential of a half-cell, E, and the photoelectric work function, W(ev), are related by W= E + 4.4. Empirical relationships between the gas-phase ionization energy and polarographic half-wave potentials are given a theoretical basis.

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Bibliographic Details
Published inChemical physics letters Vol. 42; no. 1; pp. 97 - 98
Main Author Ballard, R.E.
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.08.1976
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Summary:The standard (reduction) potential of a half-cell, E, and the photoelectric work function, W(ev), are related by W= E + 4.4. Empirical relationships between the gas-phase ionization energy and polarographic half-wave potentials are given a theoretical basis.
ISSN:0009-2614
1873-4448
DOI:10.1016/0009-2614(76)80559-3