In situ LiFePO4 nano-particles grown on few-layer graphene flakes as high-power cathode nanohybrids for lithium-ion batteries

• Published in: Nano energy Vol. 51; pp. 656 - 667
• Main Authors: Longoni, Gianluca, Panda, Jaya Kumar, Gagliani, Luca, Brescia, Rosaria, Manna, Liberato, Bonaccorso, Francesco, Pellegrini, Vittorio
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.09.2018
• Subjects: Graphene flakes; High-rate; Iron Phosphate; Liquid-phase exfoliation; Lithium-ion batteries; Lithium-ion batteries; High-rate; Graphene flakes; Liquid-phase exfoliation; Iron Phosphate
• ISSN: 2211-2855
• DOI: 10.1016/j.nanoen.2018.07.013

We have realized a Lithium Iron Phosphate (LFP)-graphene nanohybrid obtained by a direct LFP crystal colloidal synthesis on few-layer graphene (FLG) flakes produced by the liquid phase exfoliation (LPE) of pristine graphite. This hybrid material has been tested as a cathode in Li-ion batteries, achieving fast charge/discharge responses to high specific currents. We demonstrate a specific capacity exceeding 110 mAh g−1 at 20 C, with no electrode damaging. Our LFP-FLG electrodes display a low charge transfer resistance, chemical stability and steady electrochemical behavior even under stressful conditions, such as impulsive charges at a high-rate (5 C) and long cycles at 1 C (> 700 cycles). The LFP colloidal synthesis combined with the FLG production by LPE allows for tuning both the LFP-platelets like and FLG flake morphologies in order to promote an optimal connection between the LFP and FLG flakes, ensuring fast charge transfers and consequently high-rate electrochemical performances. The method here proposed yields a scalable production path, which can be easily extended to silicate-, phosphate- and fluorophosphates-based cathode materials for the next generation of high-power lithium batteries. [Display omitted] •Unravelling the role of graphene nanoflakes as a new templating material for the preparation of LiFePO4-graphene hybrid, exploited as cathode in a lithium ion battery.•Solution processing.•Hybrid electrodes.•2D nanomaterials.•Environmentally-friendly.