Electrochromic properties of poly (1-(phenyl)-2,5-di(2-thienyl)-1H-pyrrole-co-3,4-ethylenedioxy thiophene) and its application in electrochromic devices

• Published in: Optical materials Vol. 30; no. 10; pp. 1489 - 1494
• Main Authors: Tarkuc, S., Sahmetlioglu, E., Tanyeli, C., Akhmedov, I.M., Toppare, L.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.06.2008
• Subjects: Conducting polymers; Electrochemical copolymerization; Electrochromic devices; Electrochromism; Conducting polymers; 78.20.J.g; Electrochemical copolymerization; Electrochromic devices; Electrochromism
• ISSN: 0925-3467; 1873-1252
• DOI: 10.1016/j.optmat.2007.08.009

Electrochemical copolymerization of 1-(phenyl)-2,5-di(2-thienyl)-1H-pyrrole (PTP) with 3,4-ethylenedioxy thiophene (EDOT) was carried out in acetonitrile (AN)/NaClO4/LiClO4 (0.1M) solvent–electrolyte couple via potentiodynamic electrolysis. Characterizations of the resulting copolymer were performed via cyclic voltammetry (CV), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and spectroelectrochemical analysis. Spectroelectrochemical analyses show that the copolymer of PTP with EDOT has an electronic band gap (due to π to π∗ transition) of 1.9eV at 480nm, with a claret red in the fully reduced form and a blue color in the fully oxidized form. Via kinetic studies, the optical contrast (ΔT %) was found to be 8% for P(PTP-co-EDOT). Results showed that the time required to reach 95% of the ultimate transmittance was 1.7s for the copolymer. The P(PTP-co-EDOT) film was used to construct a dual type polymer electrochromic device (ECDs) with poly(3,4-ethylenedioxy thiophene) (PEDOT). Spectroelectrochemistry, electrochromic switching and open circuit memory of the device were investigated.