Synthesis of the BC/DE ring model of brevisin for confirmation of the structure around the acyclic junction

Synthesis of the BC/DE ring model of brevisin, a polycyclic ether isolated from the red tide dinoflagellate Karenia brevis, is reported. Comparison of the NMR data of the BC/DE ring model with those corresponding to the same region of brevisin led to the confirmation of its structure around the acyc...

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Bibliographic Details
Published inTetrahedron letters Vol. 51; no. 35; pp. 4673 - 4676
Main Authors Kuranaga, Takefumi, Satake, Masayuki, Baden, Daniel G., Wright, Jeffrey L.C., Tachibana, Kazuo
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 01.09.2010
Elsevier
Subjects
Aldol reaction
Chemistry
Chemistry, Organic
Dinoflagellate
Natural product
Physical Sciences
Polycyclic ether
Science & Technology
Natural product
Aldol reaction
Polycyclic ether
Dinoflagellate
SYSTEM
GAMBIEROL
POLYCYCLIC ETHERS
BREVETOXINS
DINOFLAGELLATE KARENIA-BREVIS
ABSOLUTE-CONFIGURATION
PTYCHODISCUS-BREVIS
CHEMICAL-SYNTHESIS
MAITOTOXIN
CONVERGENT STRATEGIES
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Summary:Synthesis of the BC/DE ring model of brevisin, a polycyclic ether isolated from the red tide dinoflagellate Karenia brevis, is reported. Comparison of the NMR data of the BC/DE ring model with those corresponding to the same region of brevisin led to the confirmation of its structure around the acyclic juncture.
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2010.07.001