Adsorption-desorption and leaching potential of glyphosate and aminomethylphosphonic acid in acidic Malaysian soil amended with cow dung and rice husk ash

• Published in: Environmental monitoring and assessment Vol. 190; no. 11; pp. 676 - 15
• Main Authors: Garba, Jamilu, Samsuri, Abd Wahid, Othman, Radziah, Ahmad Hamdani, Muhammad Saiful
• Format: Journal Article
• Language: English
• Published: Cham Springer International Publishing 01.11.2018; Springer Nature B.V
• Subjects: Acidic oxides; Acidic soils; Adsorption; Adsorptivity; Animals; Ashes; Atmospheric Protection/Air Quality Control/Air Pollution; Cattle; Cattle manure; Control; Desorption; Dung; Earth and Environmental Science; Ecology; Ecotoxicology; Environment; Environmental Management; Environmental monitoring; Environmental Monitoring - methods; Environmental science; Glycine - analogs & derivatives; Glycine - chemistry; Glyphosate; Groundwater; Herbicides; Herbicides - analysis; Isoxazoles - chemistry; Leaching; Mobility; Monitoring/Environmental Analysis; Oryza; Oxide minerals; Removal; Rice; Soil; Soil - chemistry; Soil amendment; Soil investigations; Soil Pollutants - analysis; Tetrazoles - chemistry; Sorption; Soil; Mobility; Organic waste; Isotherm model; Glyphosate
• ISSN: 0167-6369; 1573-2959
• DOI: 10.1007/s10661-018-7034-3

This study investigates adsorption-desorption and the leaching potential of glyphosate and aminomethylphosphonic acid (AMPA) in control and amended—addition of cow dung or rice husk ash—acidic Malaysian soil with high oxide mineral content. The addition of cow dung or rice husk ash increased the adsorptive removal of AMPA. The isotherm data of glyphosate and AMPA best fitted the Freundlich model. The constant K f for glyphosate was high in the control soil (544.873 mg g −1 ) followed by soil with cow dung (482.451 mg g −1 ) then soil with rice husk ash (418.539 mg g −1 ). However, for AMPA, soil with cow dung was high (166.636 mg g −1 ) followed by soil with rice husk ash (137.570 mg g −1 ) then the control soil (48.446 mg g −1 ). The 1/ n values for both glyphosate and AMPA adsorptions were < 1 indicating their strong affinity for adsorbents. Desorption of both glyphosate and AMPA occurred only in the control soil. The compounds were not detected in soils with added cow dung or rice husk ash. The addition of cow dung or rice husk ash increased glyphosate mobility. However, ground water ubiquity scores for both control and amended soils were < 2.8. This indicated glyphosate is a transitional herbicide; therefore, its leaching potential in the soil is low, despite the addition of cow dung or rice husk ash. Addition of these wastes decreased the mobility and leaching potential of AMPA. The addition of cow dung or rice husk ash could be beneficial in increasing adsorption and enhancing degradation of these compounds.