Ru-Catalyzed Selective C–H Functionalization of Pyridotriazoles with Acrylates

Abstract Ruthenium-catalyzed efficient and selective C–H alkenylation of pyridotriazoles with acrylates is described. The combination of metals (Ru and Fe) plays a crucial role in achieving quantitative yields of the desired products. The reaction is proposed to involve the formation of a ruthenium...

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Bibliographic Details
Published inSynOpen (2017) Vol. 5; no. 4; pp. 294 - 300
Main Authors Joshi, Abhisek, Semwal, Rashmi, Adimurthy, Subbarayappa
Format Journal Article
LanguageEnglish
Published Rüdigerstraße 14, 70469 Stuttgart, Germany Georg Thieme Verlag KG 01.10.2021
Subjects
acrylates
c–h functionalization
letter
pyridotriazoles
C–H functionalization
acrylates
pyridotriazoles
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Summary:Abstract Ruthenium-catalyzed efficient and selective C–H alkenylation of pyridotriazoles with acrylates is described. The combination of metals (Ru and Fe) plays a crucial role in achieving quantitative yields of the desired products. The reaction is proposed to involve the formation of a ruthenium cyclometalated intermediate.
ISSN:2509-9396
2509-9396
DOI:10.1055/a-1661-5655