Simulation of the reacting flow within a pilot scale calciner by means of a three phase TFM model

• Published in: Fuel processing technology Vol. 162; pp. 105 - 125
• Main Authors: Zeneli, M., Nikolopoulos, A., Nikolopoulos, N., Grammelis, P., Karellas, S., Kakaras, E.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01.07.2017; Elsevier Science Ltd
• Subjects: Calciner; Calcium carbonate; Carbon dioxide; Carbonation; Char combustion; Computational fluid dynamics; Computer simulation; Dependence; Dilution; Endothermic reactions; Energy conservation; Euler; Fluid dynamics; Fluidized beds; Freeboard; Heat exchange; Heat transfer; Heat transfer coefficients; Kinetic theory; Mathematical models; Model accuracy; Nuclear fuels; Reacting flow; Roasting; Simulation; Solid phases; Stress concentration; Temperature distribution; TFM; Three-phase flow; Two fluid models; Char combustion; TFM; Euler; Three-phase flow; Simulation; Calciner
• ISSN: 0378-3820; 1873-7188
• DOI: 10.1016/j.fuproc.2017.03.032

The aim of the present work is the 3-D CFD simulation of the reacting flow inside a pilot-scale calciner, which is part of the 1MWth dual fluidized bed (DFB) installation located at TU Darmstadt (TUD). The riser of the fluidized-bed calciner is a cylindrical tube with a height of 11.365m and a varying inner diameter equal to 0.28m near the bottom area and 0.3967m at the freeboard. The energy required for the endothermic reaction is provided by the coal combustion inside the same reactor. The gas-sorbent-fuel flow is simulated by means of the pure Eulerian Two-Fluid model (TFM), which is incorporated into the ANSYS Fluent commercial platform, with the implementation of numerous user-defined functions. Owing to the presence of two solid phases a modified version of the Kinetic Theory for Granular Flows (KTFG) for the bi-dispersed flow is applied. The advanced Energy Minimization Multi-Scale (EMMS) scheme with a new cluster correlation and the homogeneous Gidaspow model are applied for the calculation of the gas-sorbent and gas-fuel momentum exchange coefficients, respectively. Additionally, the Syamlal-Obrien symmetric model is used for the calculation of the sorbent-fuel momentum exchange coefficient. Proper reaction rates retrieved from the literature are applied for the simulation of the heterogeneous and homogeneous reactions occurring inside the reactor. Apart from the calcination of CaCO3 to CaO, the carbonation reaction is also incorporated into the numerical model, in order to observe if the reverse reaction is favored, when the temperature is below calcining conditions. The Computational Fluid Dynamics (CFD) model is validated against available experimental data regarding the pressure and temperature distribution along the riser and O2/CO2 concentrations at the calciner exit. Simulation results show that the carbonation reaction is indeed favored near the bottom bed, owing to the low temperature values, whilst the calcination rate is equal to zero. Over the height of the burner section, where the fuel enters the reactor, the temperature rises quickly to calcining conditions. Regarding the heat transfer mechanisms, it can be seen that in both solid phases the gas-solid heat exchange coefficient takes its maximum value near the bottom bed and then decreases, as the flow becomes more dilute. This fact reveals the strong dependence between the convective exchange coefficient and the solids volume fraction. Finally, concerning the CFD model accuracy, the different sub-models applied, such as drag-force models, reaction rates, heat transfer coefficients, should be further investigated in future simulations in order to enhance its validity. •CFD simulation of the reacting flow in a pilot-scale calciner•Implementation of the pure Eulerian approach with three phases (gas-solid-solid)•Application of a revised version of the KTGF for a bi-dispersed mixture•Implementation of the carbonation reaction, when temperature is below calcining conditions.