[CpRu]-catalyzed selective coupling/hydrogenation

Access to 3,4- and 3,5-disubstituted piperidine derivatives has been achieved through [Cp*Ru]-catalyzed intermolecular coupling of allylic alcohols and propargylic amides. Tandem transformation was also possible via chemoselective [Cp*Ru]-catalyzed hydrogenation of the resulting homodienes.

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Bibliographic Details
Published inCatalysis science & technology Vol. 5; no. 3; pp. 1650 - 1657
Main Authors Labed, I., Labed, A., Sun, Y., Jiang, F., Achard, M., Dérien, S., Kabouche, Z., Bruneau, C.
Format Journal Article
LanguageEnglish
Published Royal Society of Chemistry 2015
Subjects
Alcohols
Amides
Catalysis
Chemical Sciences
Derivatives
Hydrogenation
Joining
Piperidine
Transformations
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Summary:Access to 3,4- and 3,5-disubstituted piperidine derivatives has been achieved through [Cp*Ru]-catalyzed intermolecular coupling of allylic alcohols and propargylic amides. Tandem transformation was also possible via chemoselective [Cp*Ru]-catalyzed hydrogenation of the resulting homodienes.
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ISSN:2044-4753
2044-4761
DOI:10.1039/C4CY01303D