Electrical and dielectric properties of multiwall carbon nanotube/polyaniline composites

• Published in: Journal of polymer research Vol. 16; no. 4; pp. 395 - 399
• Main Authors: Shi, Sui-Lin, Zhang, Ling-Zhen, Li, Jun-Shou
• Format: Journal Article
• Language: English
• Published: Dordrecht Dordrecht : Springer Netherlands 01.07.2009; Springer Netherlands; Springer Nature B.V
• Subjects: Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Composite; Dielectric constant; Dielectric properties; electrical conductivity; Ethyl alcohol; Industrial Chemistry/Chemical Engineering; Multi wall carbon nanotubes; Multiwall carbon nanotubes; Percolation; Polyaniline; Polyanilines; Polymer Sciences; Resistivity; Studies; Thresholds; Multiwall carbon nanotubes; Electrical conductivity; Composite; Polyaniline; Dielectric properties
• ISSN: 1022-9760; 1572-8935
• DOI: 10.1007/s10965-008-9241-z

In this paper, electrical and dielectric properties of multiwall carbon nanotubes (MWCNTs)/insulating polyaniline (PANI) composites were studied. A mixture of MWCNTs and insulating polyaniline was dispersed in an ethanol solution by ultrasonic process, subsequently dried, and was hot-pressed at 200 °C under 30 MPa. Electrical and dielectric properties of the composites were measured. The experimental results show that the dc conductivities of the composites exhibit a typical percolation behavior with a low percolation threshold of 5.85 wt.% MWCNTs content. The dielectric constant of the composites increases remarkably with the increasing MWCNTs concentration, when the MWCNTs concentration was close to percolation threshold. This may be attributed to the critical behavior of the dielectric constant near the percolation threshold as well as to the polarization effects between the clusters inside the composites.