Sources and influences of atmospheric nonpolar organic compounds in Nanchang, central China: Full-year monitoring with a focus on winter pollution episodes

• Published in: The Science of the total environment Vol. 912; p. 169216
• Main Authors: Guo, Wei, Li, Zicong, Zhang, Ziyue, Zhu, Renguo, Xiao, Hongwei, Xiao, Huayun
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 20.02.2024
• Subjects: Aerosols - analysis; Air Pollutants - analysis; Alkanes - analysis; China; Coal - analysis; Environmental Monitoring; Humans; N-alkanes; NPOCs; Organic aerosols; Organic Chemicals - analysis; Particulate Matter - analysis; Pentacyclic Triterpenes - analysis; PM2.5; Polycyclic Aromatic Hydrocarbons - analysis; Seasons; Source identification; Vehicle Emissions - analysis; China; Organic aerosols; Source identification; N-alkanes; NPOCs; PM2.5; PM(2.5)
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2023.169216

Nonpolar organic compounds (NPOCs) are found in atmospheric aerosols and have significant implications for environmental and human health. Although many studies have quantitatively estimated the sources of NPOCs in different cities, few have evaluated their main influencing factors (e.g., emissions and meteorological conditions) at relatively long (e.g., different seasons) and short timescales (e.g., several days during pollution episodes). A better understanding of this issue could optimise strategies for dealing with organic contamination in atmospheric particulate matter. NPOCs (including n-alkanes, PAHs and hopanes) in fine particulate matter (PM2.5) were sampled daily at Nanchang, China, from 1 November 2020 to 31 October 2021. Analyses of specific biomarkers and diagnostic ratios indicate that the NPOCs mainly had anthropogenic sources. The quantitative estimates of a positive matrix factorization model show that fossil fuel and biomass combustion were the main sources of n-alkanes (contributing 64.8 %), while vehicle exhaust was the main source of PAHs (47.0 %) and hopanes (52.3 %). Seasonally, the contributions from coal and/or biomass combustion were higher in autumn and winter (40.2–56.3 %) than in spring and summer (25.7–44.3 %), while contributions from natural plants, petroleum volatilization and vehicle exhaust were higher in spring and summer (14.7–63.5 %) than in autumn and winter (8.1–48.9 %). Redundancy analysis shows that increased emissions, especially from coal and/or biomass combustion, are the main cause of increases in NPOCs, during both annual sampling periods and winter pollution episodes. Over the year, higher temperature and longer sunshine hours correspond to lower NPOC concentrations. In winter pollution episodes, increases in temperature and relative humidity correspond to increases in NPOC concentrations. Our results suggest that controlling primary emissions, especially from coal and biomass combustion, may be an effective way to prevent increases in NPOC concentrations. [Display omitted] •NPOCs were analysed in PM2.5 samples collected daily over one year in Nanchang.•Combustion (> 35 %) and vehicle exhaust (> 45 %) were the main sources of NPOCs.•Combustion emissions increase NPOCs to different degrees at different timescales.