New insights into thermodynamic description of strain-induced crystallization of peroxide cross-linked natural rubber filled with clay by tube model

• Published in: Polymer (Guilford) Vol. 52; no. 14; pp. 3234 - 3242
• Main Authors: Nie, Yijing, Huang, Guangsu, Qu, Liangliang, Wang, Xiaoan, Weng, Gengsheng, Wu, Jinrong
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 22.06.2011; Elsevier
• Subjects: Applied sciences; Clay (material); Composites; Crystallization; Entropy; Exact sciences and technology; Forms of application and semi-finished materials; Mathematical models; Nanocomposite; Natural rubber; Polymer industry, paints, wood; Reduction; Rubber; Technology of polymers; Thermodynamics; Tube model; Nanocomposite; Tube model; Crystallization; Clay; Deformation; Montmorillonite; Stress strain relation; Natural rubber; Experimental study; Modeling; Tensile stress; Crosslinked polymer; Isothermal crystallization; Elongation (mechanics)
• ISSN: 0032-3861; 1873-2291
• DOI: 10.1016/j.polymer.2011.05.004

Clay changes the strain-induced crystallization behavior of natural rubber and induces a dual crystallization mechanism due to the orientation of clay layers during deformation. The structure evolution was probed by in-situ synchrotron wide-angle X-ray diffraction, while the thermodynamics of the onset of crystallization was analyzed by the tube model. The entropy change required for the onset of the strain-induced crystallization of the clay filled rubber is composed of the entropy reduction due to the rubber–filler interactions and also the stretching. The summation of the two kinds of the entropy reduction is nearly equal to that of the neat rubber. The thermodynamic analysis reveals that the orientation of clay layers along the direction of stretching reduces the chain conformational entropy and changes the crystallization mechanism. These results give some new insights into the strain-induced crystallization process and the reinforcement mechanism for the clay filled rubber. [Display omitted]