Fate and removal of antimony in response to stringent control activities after a mine tailing spill

• Published in: The Science of the total environment Vol. 693; p. 133604
• Main Authors: Guo, F., Wu, F.C., Yu, F., Bai, Y.C., Fu, Z.Y., Zhu, Y.R., Guo, W.J.
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 25.11.2019
• Subjects: Antimony; Geochemical behaviour; Stringent control activities; Tailing spill; Tailing spill; Stringent control activities; Antimony; Geochemical behaviour
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2019.133604

When tailing spill accidents occur, the risk of contamination by antimony (Sb) tailings into adjacent rivers, sediments, aquifers and soil environments is high. The Sb concentrations in water and sediment under different stringent control activities were investigated for 60 days in the Jialing River basin after a tailing spill accident. Both reservoir regulation and the construction of a temporary dam with coagulation dosing remarkably reduced the Sb levels in the river water. The increase in dissolved Sb caused by the spill was reduced from ~400 μg/L in the inflow to ~200 μg/L in the outflow by reservoir regulation. Moreover, reservoir regulation led to a high concentration of Sb in the reservoir sediment, which was difficult to remove and may cause subsequent unpredictable long-term ecological and health risks. In contrast, the Sb-enriched deposition inside the temporary dam was convenient to remove. Notably, temperature alternations between day and night in winter resulted in a large fluctuation in coagulation efficiency, which may cause the failure of stringent control projects. The results of this study suggest potential improvements to stringent control activities after mine tailing accidents to mitigate environmental impacts and prevent secondary risks. [Display omitted] •Reservoir regulation and temporary dam both remarkably reduced Sb level in water.•Reservoir regulation in spill led to high level of Sb in sediments and pore water.•Temperature alternations caused fluctuation of coagulation treatment efficiency.