Enhanced removal of refractory humic- and fulvic-like organics from biotreated landfill leachate by ozonation in packed bubble columns

• Published in: The Science of the total environment Vol. 807; no. Pt 1; p. 150762
• Main Authors: Yang, Xuetong, De Buyck, Pieter-Jan, Zhang, Rui, Manhaeghe, Dave, Wang, Hao, Chen, Licai, Zhao, Yunliang, Demeestere, Kristof, Van Hulle, Stijn W.H.
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 10.02.2022
• Subjects: Biotreated landfill leachate; Humic and fulvic acids; Humic Substances - analysis; Lava rocks; Ozone; Packed bubble columns; Waste Water; Water Pollutants, Chemical - analysis; Water Purification; Biotreated landfill leachate; O3; Packed bubble columns; Humic and fulvic acids; Lava rocks; O
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2021.150762

Biotreated landfill leachate contains much refractory organics such as humic and fulvic acids, which can be degraded by O3. However, the low O3 mass transfer and high energy cost limit its wide application in landfill leachate treatment. Previous studies proved that packed bubble columns could enhance the O3 mass transfer and increase the synthetic humic acids wastewater degradation, but the performance of packed bubble columns in real wastewater treatment has not been investigated. Therefore, this study aims to evaluate the feasibility of application of packed bubble column in the real biotreated landfill leachates treatment and provide insights into the transformation of organic matters in leachates during ozonation. Packed bubble columns with lava rocks or metal pall rings (LBC or MBC) were applied and compared with a non-packed bubble column (BC). At an applied O3 dose of 8.35 mg/(Lwater sample min), the initial COD (400 mg/L) was only removed for 26% in BC and 32% in MBC while this was 46% in LBC, indicating LBC has the best performance. GC–MS analysis shows that raw biotreated leachate contains potential endocrine disruptors such as di(2-ethylhexyl) phthalate (DEHP). 61% of DEHP was removed in LBC and the least intermediate oxidation products from humic- and fulvic-like organics was detected in LBC. The highest O3 utilization efficiency (89%) and hydroxyl radical (OH) exposure rate (3.0 × 10-10 M s) were observed in LBC with lowest energy consumption (EEO) for COD removal of 18 kWh/m3. The enhanced ozonation efficiency in LBC and MBC was attributed to the improved O3 mass transfer. Besides, LBC had additional adsorptive and catalytic activity that promoted the decomposition of O3 to generate OH. This study demonstrates that a packed bubble column increases removal and decreases energy use when treating landfill leachate, thus promoting the application of ozonation. [Display omitted] •O3 columns were packed with lava rocks or metal pall rings to treat landfill leachate.•Improved O3 utilization efficiency (>80%) and OH exposure rate (>2.2×10-10 M s)•Higher COD removal (>32%) with less energy consumption (<30 kWh/m3)•Less intermediate products formed.•The Fe element in lava rocks is involved in the catalytic O3 decomposition.