New Copper Bromide Organic-Inorganic Hybrid Molecular Compounds with Anionic Inorganic Core and Cationic Organic Ligands

Here, organic-inorganic hybrid molecular compounds based on copper(I) bromide have been synthesized by slow-diffusion method. The inorganic modules of these two structures are Cu2Br42− anion, and the inorganic modules are coordinated to cationic organic ligands via Cu-N coordinative bonds. Both of t...

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Bibliographic Details
Published inCrystals (Basel) Vol. 12; no. 1; p. 19
Main Authors Luo, Dawei, Zhang, Jian, Liang, Yu, Ni, Jianling, Wang, Fangming, Liu, Wei
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 01.01.2022
Subjects
Binding sites
Cations
Chemical bonds
Copper
Copper bromide
Diffusion rate
Efficiency
Ligands
luminescence
Modules
organic-inorganic hybrid
Single crystals
Spectrum analysis
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Summary:Here, organic-inorganic hybrid molecular compounds based on copper(I) bromide have been synthesized by slow-diffusion method. The inorganic modules of these two structures are Cu2Br42− anion, and the inorganic modules are coordinated to cationic organic ligands via Cu-N coordinative bonds. Both of these compounds are luminescent, emitting green emissions under UV excitation.
ISSN:2073-4352
2073-4352
DOI:10.3390/cryst12010019