A method for the selective reduction of carbohydrate 4,6- O-benzylidene acetals

Glucose-derived 4,6- O-benzylidene acetals can be selectively reduced to the corresponding 6- O-benzyl derivatives by the treatment with trifluoroacetic acid and triethylsilane. Glucose-derived 4,6- O-benzylidene acetals can be selectively reduced to the corresponding 6- O-benzyl derivatives by the...

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Bibliographic Details
Published inTetrahedron letters Vol. 36; no. 5; pp. 669 - 672
Main Authors DeNinno, Michael P., Etienne, John B., Duplantier, Kimberly C.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 01.01.1995
Elsevier
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
GLYCOSIDES
BENZYLIDENE ACETALS
CLEAVAGE
DERIVATIVES
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Summary:Glucose-derived 4,6- O-benzylidene acetals can be selectively reduced to the corresponding 6- O-benzyl derivatives by the treatment with trifluoroacetic acid and triethylsilane. Glucose-derived 4,6- O-benzylidene acetals can be selectively reduced to the corresponding 6- O-benzyl derivatives by the treatment with trifluoroacetic acid and triethylsilane.
ISSN:0040-4039
1873-3581
DOI:10.1016/0040-4039(94)02348-F