Liquid-phase PVT data of alkylbenzenes

Liquid-phase PVT data are presented at 318.15 and 33.15 K for pressures up to 5 MPa for toluene, ethylbenzene, propylbenzene, isopropylbenzene and butylbenzene and for equimolar mixtures of the others with isopropylbenzene. The constants of an equation describing the observed P-V behaviour and calcu...

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Bibliographic Details
Published inFluid phase equilibria Vol. 64; pp. 237 - 249
Main Authors Chyliński, K., Gregorowicz, J.
Format Journal Article
LanguageEnglish
Published Amsterdam Elsevier B.V 1991
Elsevier Science
Subjects
Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
Liquid phase
Experimental study
Thermodynamic properties
PVT relation
Isothermal compressibility
Organic compounds
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Summary:Liquid-phase PVT data are presented at 318.15 and 33.15 K for pressures up to 5 MPa for toluene, ethylbenzene, propylbenzene, isopropylbenzene and butylbenzene and for equimolar mixtures of the others with isopropylbenzene. The constants of an equation describing the observed P-V behaviour and calculated isothermal compressibilities at zero pressure for each liquid are also reported. Results for pure liquids as well as small values of excess volumes and compressibilities for the mixtures studied suggest that alkyl group length and structure influence the differences in the observed properties.
ISSN:0378-3812
1879-0224
DOI:10.1016/0378-3812(91)90016-Z