Visible light organic photoredox catalytic cascade reactions

Over the past years, impressive progress has been made in the development of organic photoredox catalytic cascade reactions without the participation of expensive and toxic transition metals under visible light irradiation. These transformations highly depend on the in situ generation of various rad...

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Published inChemical communications (Cambridge, England) Vol. 57; no. 96; pp. 12914 - 12935
Main Authors Xu, Guo-Qiang, Xu, Peng-Fei
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 03.12.2021
Subjects
Biocompatibility
Cascade chemical reactions
irradiation
light
Light irradiation
Photoredox catalysis
redox reactions
toxicity
Transition metals
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Summary:Over the past years, impressive progress has been made in the development of organic photoredox catalytic cascade reactions without the participation of expensive and toxic transition metals under visible light irradiation. These transformations highly depend on the in situ generation of various radical species in the photoredox catalytic cycles. Numerous chemically and biomedically valuable building blocks have been synthesized through this efficient and sustainable protocol. In this review, we highlight the recent progress in this blooming area by presenting a series of new catalytic cascade reactions mediated by organic photoredox catalysts and describe their mechanisms and applications which have appeared in the recent literature. We highlight the recent advances in the field of organic photoredox catalytic cascade reactions and describe their mechanisms and applications in organic synthesis.
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/d1cc04883j