Mesoscale Modeling of Exploiting Methane Hydrate by CO2 Replacement in Homogeneous Porous Media

• Published in: International journal of heat and mass transfer Vol. 158; p. 119741
• Main Authors: Hsieh, Pei-Ying, Sean, Wu-Yang, Sato, Toru, Seo, Yong-Won
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01.09.2020; Elsevier BV
• Subjects: Carbon dioxide; CO2 replacement; computational fluid dynamics; Computer simulation; Energy of dissociation; Flux; Free energy; Gas hydrate dissociation; homogeneous porous media; Kinetic theory; Mesoscale phenomena; Methane hydrates; Modelling; Porosity; Porous media; Pressure effects; Silicon dioxide; Unstructured grids (mathematics); Void fraction; Gas hydrate dissociation; CO2 replacement; homogeneous porous media; computational fluid dynamics
• ISSN: 0017-9310; 1879-2189
• DOI: 10.1016/j.ijheatmasstransfer.2020.119741

•A new modeling of replacement process is established by considering the individual flux of hydrate surface at stable and unstable regions of CH4 hydrate. At stable CH4 and CO2 hydrates region, it provides a simple situation of discussing the recovery process which CO2 guest particle replaces CH4 in hydrate due to free energy difference. Here, the formation rate of CO2 hydrate is dominated by the dissociation rate of CH4. However, large amount of CH4 dissociated at the surface of hydrate at unstable region. The formation rate become dominated by the formation flux of CO2 hydrate itself. In addition, the high-pressure effect of accelerating the guest gas trapped in hydrate is also considered by applying kinetic theory of gases.•For supporting molecular simulation, and field-scale simulators, we aim at establishing mesoscale modeling to analyze the simultaneous kinematic displacement process including CO2H formation, MH dissociation and their exchange in non-equilibrium states.•To use kinematic surface displacement modeling and CFD method to analyze momentum, mass, and heat transfer is a simple way of estimating the displacement rate by injecting CO2 in MH core. In this study, the objective is to establish a general mesoscale model for replacement so as to precisely estimate the flux of methane hydrate dissociation and CO2 hydrate formation in the cage of hydrate. If homogeneous porous media is assumed, porosity (void fraction) of methane hydrate sediment can be obtained from silica packing in experiment. Based on considering the driving force of free energy in dissociation and formation processes, a new modeling of replacement process is established by considering the individual flux of hydrate surface at stable and unstable regions of CH4 hydrate. At stable CH4 and CO2 hydrates region, it provides a simple situation of discussing the recovery process which CO2 guest particle replaces CH4 in hydrate due to free energy difference. Here, the formation rate of CO2 hydrate is dominated by the dissociation rate of CH4. However, large amount of CH4 dissociated at the surface of hydrate at unstable region. The formation rate become dominated by the formation flux of CO2 hydrate itself. In addition, the high-pressure effect of accelerating the guest gas trapped in hydrate is also considered by applying kinetic theory of gases. By applying CFD method and unstructured grid, it is possible to consider momentum, concentration and thermal distributions in non-equilibrium state simultaneously. To compare with experimental results, flux of methane hydrate dissociation at high surface concentration in simulation are consistent with experiment.