Vapor pressure measurement for binary and ternary systems containing a phosphoric ionic liquid

• Published in: Fluid phase equilibria Vol. 247; no. 1; pp. 190 - 198
• Main Authors: Zhao, Jin, Jiang, Xiao-Chuan, Li, Chun-Xi, Wang, Zi-Hao
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 15.09.2006; Elsevier Science
• Subjects: Chemical thermodynamics; Chemistry; Exact sciences and technology; General and physical chemistry; Ionic liquid; Measurement; Mixtures; NRTL model; Prediction; Thermodynamic properties; Vapor pressure; Measurement; NRTL model; Vapor pressure; Prediction; Ionic liquid; Water; Ternary system; Ethanol; Binary system; Alcohol; Primary alcohol; Thermodynamic model; Non random two liquid model; Pressure measurement; Thermodynamic properties
• ISSN: 0378-3812; 1879-0224
• DOI: 10.1016/j.fluid.2006.07.007

Vapor pressure data were measured for nine binary systems containing water, methanol or ethanol with the ionic liquids 1-methyl-3-methylimidazolium dimethylphosphate ([MMIM][DMP]), 1-ethyl-3-methylimidazolium diethylphosphate ([EMIM][DEP]) and 1-butyl-3-methylimidazolium dibutylphosphate ([BMIM][DBP]) and one ternary system ethanol–water–[MMIM][DMP] at varying temperature and ionic liquid mass percent ranging from 10% to 70% by a quasi-static method. The vapor pressure data of the binary systems were correlated by NRTL model with overall average absolute relative deviation (ARD) of 0.89% and a maximum ARD within 2%. Based on the vapor pressure depression of binary systems interpolated at ionic liquid mole fraction 0.05 in the temperature range from 280 to 370 K, it is shown that the effect of ionic liquid on the vapor pressure lowering follows the order [MMIM][DMP] > [EMIM][DEP] > [BMIM][DBP] for water, and [BMIM][DBP] > [EMIM][DEP] > [MMIM][DMP] for methanol and ethanol, suggesting that the “ionic” characteristic of the ionic liquid dominates in water, while the “molecule” characteristic prevails in organic solvent. The binary NRTL parameters were used to predict the vapor pressure of the ternary system ethanol–water–[MMIM][DMP] with an ARD of 2.8% and the maximum relative deviation of −5.43%.