Thermal properties of tris(1,10-phenanthroline) complexes of iron(II) and nickel(II) salts

Thermal behaviour of the complexes [ M(phen) 3] X 2·nH 2O has been studied in static air and vacuum atmospheres (where M = Fe(II), Ni(II); phen = 1, 10-phenanthroline; and X = Cl, Br, I, SCN). The intermediate derivatives of the thermal decomposition of these complexes having composition M(phen) 2 X...

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Published inJournal of inorganic & nuclear chemistry Vol. 35; no. 8; pp. 2679 - 2690
Main Authors Akabori, Kozo, Matsuo, Hiroshi, Yamamoto, Yuroku
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.01.1973
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Summary:Thermal behaviour of the complexes [ M(phen) 3] X 2·nH 2O has been studied in static air and vacuum atmospheres (where M = Fe(II), Ni(II); phen = 1, 10-phenanthroline; and X = Cl, Br, I, SCN). The intermediate derivatives of the thermal decomposition of these complexes having composition M(phen) 2 X 2 are isolated in the furnace of DTA-TG apparatus under vacuum atmospheric conditions. Structures are assigned to these intermediate complexes on the basis of analytical data, reflectance spectra, magnetic moments and X-ray powder diffraction patterns.
ISSN:0022-1902
1878-1225
DOI:10.1016/0022-1902(73)80498-1