A heterogeneous catalytic method for the conversion of nitriles into amides using molecular sieves modified with copper(II)

A heterogenous catalytic method is developed for the hydration of nitriles into amides with acetaldoxime. Copper(II) supported on 4 Å molecular sieves is an efficient catalyst for this reaction.

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Bibliographic Details
Published inTetrahedron letters Vol. 52; no. 45; pp. 6021 - 6023
Main Authors Kiss, Árpád, Hell, Zoltán
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 09.11.2011
Elsevier
Subjects
Acetaldoxime
Aliphatic compounds
Amide
Amides
Catalysis
Catalysts
Catalysts: preparations and properties
Catalytic reactions
Chemistry
Chemistry, Organic
Conversion
Copper
Exact sciences and technology
General and physical chemistry
Heterogeneous catalysis
Hydration
Molecular sieves
Nitrile
Nitriles
Organic chemistry
Palladium
Physical Sciences
Preparations and properties
Science & Technology
Tetrahedrons
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Heterogeneous catalysis
Amide
Palladium
Nitrile
Acetaldoxime
Copper
TRANSFORMATION
ACID
COMPLEXES
HYDROLYSIS
HYDRATION
ALUMINA
WATER
Copper II
Catalytic reaction
Hydration
Transition metal
Molecular sieve
Copper ion
Aldoxime
Carboxamide
Platinoid
Catalyst
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Summary:A heterogenous catalytic method is developed for the hydration of nitriles into amides with acetaldoxime. Copper(II) supported on 4 Å molecular sieves is an efficient catalyst for this reaction.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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content type line 23
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2011.09.012