The effect of surface chemistry of graphene on rheological and electrical properties of polymethylmethacrylate composites

• Published in: Carbon (New York) Vol. 50; no. 14; pp. 5117 - 5125
• Main Authors: Zhang, Hao-Bin, Zheng, Wen-Ge, Yan, Qing, Jiang, Zhi-Guo, Yu, Zhong-Zhen
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 01.11.2012; Elsevier
• Subjects: Carbon; Chemistry; Cross-disciplinary physics: materials science; rheology; Electromagnetic interference; Exact sciences and technology; Fullerenes and related materials; diamonds, graphite; General and physical chemistry; Graphene; Materials science; Oxygen content; Physics; Polymethyl methacrylates; Rheological properties; Shielding; Specific materials; Surface chemistry; Surface physical chemistry; Viscoelasticity; Oxygen; Storage modulus; Electrical properties; Microwave radiation; Surface chemistry; Dispersions; Low frequency; Mechanism; Interfaces; Absorption; Composite materials; PMMA; Graphene; Percolation; Polarity; Solids; Rheological properties
• ISSN: 0008-6223; 1873-3891
• DOI: 10.1016/j.carbon.2012.06.052

Graphene sheets with different oxygen contents were prepared to functionalize the electrically insulating polymethylmethacrylate (PMMA). The influences of surface chemistry of graphene on rheological, electrical and electromagnetic interference (EMI) shielding properties of its PMMA composites were investigated. The appearance of frequency-independent storage modulus at low frequency suggests a solid-like viscoelastic behavior and the formation of an interconnected network of graphene in the matrix. Due to the favorable interfacial interactions arising from polarity matching, the graphene with a C/O ratio of 13.2 (graphene-13.2) shows a better dispersion in PMMA than those with lower C/O ratios, and thus its PMMA composites exhibit lower rheological and electrical percolation thresholds. The EMI shielding properties of the graphene/PMMA composites exhibit similar dependence on the oxygen content of graphene. A high EMI shielding effectiveness of ∼30dB was obtained for the PMMA composite with 4.2vol.% of graphene-13.2 with microwave absorption as the dominant EMI shielding mechanism.