A general and convenient route to oxazolyl ligands

A diverse range of chiral and achiral oxazolyl ligands, which have many applications including catalysis and luminescent devices, are synthesized simply in three steps from readily available and inexpensive phenol and amino alcohol starting materials. The method can be applied to ligands with electr...

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Bibliographic Details
Published inTetrahedron letters Vol. 52; no. 40; pp. 5120 - 5123
Main Authors Aspinall, Helen C., Beckingham, Oliver, Farrar, Michael D., Greeves, Nicholas, Thomas, Christopher D.
Format Journal Article
LanguageEnglish
Published OXFORD Elsevier Ltd 05.10.2011
Elsevier
Subjects
Alcohols
Catalysis
Chemistry
Chemistry, Organic
Chiral ligand
Devices
Exact sciences and technology
Heterocyclic compounds
Heterocyclic compounds with n hetero atom and also o and/or s, se, te hetero atoms
Ligands
Noncondensed benzenic compounds
Organic chemistry
Oxazoline
Oxazolyl ligand
Oxazolyl phenol
Phenol
Physical Sciences
Preparations and properties
Science & Technology
Tetrahedrons
Oxazolyl ligand
Oxazolyl phenol
Chiral ligand
Oxazoline
SELECTIVE REACTIONS
ZN(HPB)
PHENOLS
CONVERSION
COMPLEXES
ALDEHYDES
Ligand
Oxazoline derivatives
Phenols
Chiral compound
Chemical synthesis
Oxazole derivatives
Oxygen nitrogen heterocycle
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Summary:A diverse range of chiral and achiral oxazolyl ligands, which have many applications including catalysis and luminescent devices, are synthesized simply in three steps from readily available and inexpensive phenol and amino alcohol starting materials. The method can be applied to ligands with electron-donating/-withdrawing and sterically demanding/undemanding substituents, and can conveniently be scaled up to >25 g of product.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0040-4039
1873-3581
DOI:10.1016/j.tetlet.2011.07.070