Sorption behavior and preliminary pervaporation results of cross-linked polyvinylalcohol and polydimethylsiloxane membranes prepared for the separation of water-ethylacetate mixtures

• Published in: Chemical engineering communications Vol. 190; no. 5-8; pp. 564 - 572
• Main Authors: Salt, Y., Hasanoğlu, A., Dinçer, S.
• Format: Journal Article
• Language: English
• Published: Taylor & Francis Group 01.05.2003
• Subjects: Pervaporation; Polydimethylsiloxane; Polyvinylalcohol; Sorption; Tartaric Acid
• ISSN: 0098-6445; 1563-5201
• DOI: 10.1080/00986440302121

Since pervaporation process is the coupling of solution and diffusion mechanisms, a sorption study was carried out with membranes prepared by cross-linking polyvinylalcohol (PVA) and polidimethylsiloxane (PDMS). Tartaric acid (Tac) was used as the cross-linking agent for PVA, and a commercial cross-linking agent was used for PDMS. Sorption experiments were carried out at 30-50°C temperature range in pure water and ethyl acetate using the films prepared. The PVA and PDMS films prepared preferentially sorb water and ethylacetate, respectively. A pervaporation study at 30°C was carried out for pure ethylacetate and pure water, and mixtures of ethylacetate containing 2 and 2.5 wt% water using 100 w m thick PVA membrane. The results indicate that the PVA membrane prepared is extremely selective for water.