On the Electrical and Optical Properties of Some Poly(Azomethine Sulfone)s in Thin Films

• Published in: Journal of macromolecular science. Physics Vol. 50; no. 7; pp. 1285 - 1297
• Main Authors: Rusu, Mihaela, Airinei, Anton, Rusu, George G., Marin, LuminiŢA, Cozan, Vasile, RÂmbu, Petronela, Caplanus, Ion, Rusu, Gheorghe I.
• Format: Journal Article
• Language: English
• Published: Philadelphia, PA Taylor & Francis Group 01.07.2011; Taylor & Francis
• Subjects: Applied sciences; Conjugation; Electrical conduction; electrical properties; Electronics; Exact sciences and technology; Glass; Mathematical models; optical properties; Organic polymers; Physicochemistry of polymers; poly(azomethine sulfone)s; Polycondensation; Polymers; Preparation, kinetics, thermodynamics, mechanism and catalysts; Thermistors; Thin films; Electrical conductivity; Electrical properties; Temperature effect; Composition effect; Seebeck effect; Condensation polymerization; poly(azomethine sulfone)s; Experimental study; Sulfone copolymer; Absorption spectrum; thin films; Optical properties; Preparation; Aromatic copolymer; Schiff base copolymer
• ISSN: 0022-2348; 1525-609X
• DOI: 10.1080/00222348.2010.507444

Poly(azomethine sulfone)s were synthesized by reacting 4,4′-sulfonyl bis(4-chlorophenyl) with 2,2-bis(4-hydroxyphenyl)propane and azomethine bisphenol in different molar ratios. Thin films were deposited from solution onto glass substrates. Study of the temperature dependences of the electrical conductivity, σ, and Seebeck coefficient, S, were performed in the temperature range 300 K-500 K. Thermal activation energies of electrical conduction, E a , calculated from these dependences, ranged between 1.50 eV and 1.85 eV. The values of E a were smaller for polymers with extended conjugation systems. The possibility to use the polymers in thermistor technology is discussed. The aspect of the temperature dependences of σ and S shows that a model based on the energy band-gap representation can be successfully used for explaining the electronic transport mechanism in the higher temperature range. In the lower temperature range, the mechanism of the electrical conduction is discussed in terms of the Mott variable range hopping conduction. The values of some optical parameters (absorption coefficient, optical band gap, etc.) were determined from transmission spectra.