Thermal and mechanical evaluation of cyanate ester resin modified with bismaleimide and diallyl phthalate

• Published in: Polymers for advanced technologies Vol. 21; no. 9; pp. 640 - 645
• Main Authors: He, Shaobo, Liang, Guozheng, Yan, Hongxia, Wang, Jinhe, Yang, Lianli
• Format: Journal Article
• Language: English
• Published: Chichester, UK John Wiley & Sons, Ltd 01.09.2010
• Subjects: bismaleimide; Bismaleimides; bisphenol A dicyanate; Blends; Cyanates; diallyl phthalate; Dynamical systems; Dynamics; Esters; mechanical properties; Polymers; Resins; thermal properties
• ISSN: 1042-7147; 1099-1581; 1099-1581
• DOI: 10.1002/pat.1477

Cyanate ester resins have excellent dielectric, mechanical, and thermal properties; however, their major drawback is their brittleness. A high performance matrix blend was developed using bisphenol A dicyanate (BADCy), bismaleimide (BMI) and diallyl phthalate (DAP), and Cobalt (III) acetylacetonate dissolved in nonyl phenol (NP) as a complex catalyst system for BADCy. The properties of the BADCy/BMI/DAP blends, such as thermal and mechanical properties, were investigated in detail by dynamic mechanical analysis (DMA), thermogravimetric analysis (TGA), and mechanical measurement. The results show that the addition of the appropriate amount of DAP and BMI can improve the impact strength and the flexural strength and this possibly comes from forming an interpenetrating polymer network in the systems. However, the thermal stability of the blends was found to be lower than that of the unmodified BADCy resin. Copyright © 2009 John Wiley & Sons, Ltd.