Squaramide‐Catalyzed Asymmetric Reactions

Bifunctional squaramides have emerged as powerful hydrogen‐bonding catalysts for promoting a wide array of useful asymmetric reactions, which provides convenient methods for the construction of complex molecular structures and chiral biologically active compounds. This review highlights the recent a...

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Published inChemical record Vol. 17; no. 10; pp. 994 - 1018
Main Authors Zhao, Bo‐Liang, Li, Jun‐Hua, Du, Da‐Ming
Format Journal Article
LanguageEnglish
Published United States Wiley Subscription Services, Inc 01.10.2017
Subjects
asymmetric synthesis
Asymmetry
Bioactive compounds
Biological activity
Cascade chemical reactions
cascade reaction
Catalysts
Chemical bonds
Chemical reactions
Construction methods
hydrogen bond
Hydrogen bonding
Mannich reaction
Michael addition
organocatalysis squaramides
Michael addition
organocatalysis squaramides
asymmetric synthesis
cascade reaction
Mannich reaction
hydrogen bond
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Abstract Bifunctional squaramides have emerged as powerful hydrogen‐bonding catalysts for promoting a wide array of useful asymmetric reactions, which provides convenient methods for the construction of complex molecular structures and chiral biologically active compounds. This review highlights the recent advances of our research group in the chiral squaramide‐catalyzed asymmetric reactions, including Michael addition, Mannich reaction, aza‐Henry reaction, Strecker reaction as well as cascade or sequential reactions. Bifunctional squaramides have emerged as powerful hydrogen‐bonding catalysts for promoting a wide array of useful asymmetric reactions, which provides convenient methods for the construction of complex molecular structures and chiral biologically active compounds. This review highlights the recent advances of our research group in the chiral squaramide‐catalyzed asymmetric reactions, including Michael addition, Mannich reaction, aza‐Henry reaction, Strecker reaction as well as cascade or sequential reactions.
AbstractList Bifunctional squaramides have emerged as powerful hydrogen‐bonding catalysts for promoting a wide array of useful asymmetric reactions, which provides convenient methods for the construction of complex molecular structures and chiral biologically active compounds. This review highlights the recent advances of our research group in the chiral squaramide‐catalyzed asymmetric reactions, including Michael addition, Mannich reaction, aza‐Henry reaction, Strecker reaction as well as cascade or sequential reactions.
Bifunctional squaramides have emerged as powerful hydrogen‐bonding catalysts for promoting a wide array of useful asymmetric reactions, which provides convenient methods for the construction of complex molecular structures and chiral biologically active compounds. This review highlights the recent advances of our research group in the chiral squaramide‐catalyzed asymmetric reactions, including Michael addition, Mannich reaction, aza‐Henry reaction, Strecker reaction as well as cascade or sequential reactions. Bifunctional squaramides have emerged as powerful hydrogen‐bonding catalysts for promoting a wide array of useful asymmetric reactions, which provides convenient methods for the construction of complex molecular structures and chiral biologically active compounds. This review highlights the recent advances of our research group in the chiral squaramide‐catalyzed asymmetric reactions, including Michael addition, Mannich reaction, aza‐Henry reaction, Strecker reaction as well as cascade or sequential reactions.
Bifunctional squaramides have emerged as powerful hydrogen-bonding catalysts for promoting a wide array of useful asymmetric reactions, which provides convenient methods for the construction of complex molecular structures and chiral biologically active compounds. This review highlights the recent advances of our research group in the chiral squaramide-catalyzed asymmetric reactions, including Michael addition, Mannich reaction, aza-Henry reaction, Strecker reaction as well as cascade or sequential reactions.Bifunctional squaramides have emerged as powerful hydrogen-bonding catalysts for promoting a wide array of useful asymmetric reactions, which provides convenient methods for the construction of complex molecular structures and chiral biologically active compounds. This review highlights the recent advances of our research group in the chiral squaramide-catalyzed asymmetric reactions, including Michael addition, Mannich reaction, aza-Henry reaction, Strecker reaction as well as cascade or sequential reactions.
Author Li, Jun‐Hua
Zhao, Bo‐Liang
Du, Da‐Ming
Author_xml – sequence: 1
  givenname: Bo‐Liang
  surname: Zhao
  fullname: Zhao, Bo‐Liang
  organization: Beijing Institute of Technology
– sequence: 2
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  surname: Li
  fullname: Li, Jun‐Hua
  organization: Beijing Institute of Technology
– sequence: 3
  givenname: Da‐Ming
  surname: Du
  fullname: Du, Da‐Ming
  email: dudm@bit.edu.cn
  organization: Beijing Institute of Technology
BackLink https://www.ncbi.nlm.nih.gov/pubmed/28266131$$D View this record in MEDLINE/PubMed
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Issue 10
Keywords Michael addition
organocatalysis squaramides
asymmetric synthesis
cascade reaction
Mannich reaction
hydrogen bond
Language English
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2016; 3
2015; 357
2005; 127
2010; 132
2013; 135
2012 2012; 124 51
2015
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2005; 3
2008; 41
2012; 48
2011; 47
2008; 81
2001 2001; 40 113
2006; 106
2012; 44
2009; 38
2008; 130
2012; 41
2012; 8
2014; 32
e_1_2_6_114_2
e_1_2_6_53_2
e_1_2_6_137_2
e_1_2_6_30_2
e_1_2_6_91_2
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e_1_2_6_198_2
e_1_2_6_175_2
e_1_2_6_212_1
e_1_2_6_38_2
e_1_2_6_76_2
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e_1_2_6_99_2
e_1_2_6_102_2
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e_1_2_6_64_2
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e_1_2_6_26_2
e_1_2_6_113_2
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e_1_2_6_54_1
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e_1_2_6_197_2
e_1_2_6_151_1
e_1_2_6_211_1
e_1_2_6_219_1
e_1_2_6_39_2
e_1_2_6_77_2
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e_1_2_6_124_2
e_1_2_6_147_1
e_1_2_6_42_2
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e_1_2_6_80_2
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e_1_2_6_74_2
e_1_2_6_150_1
e_1_2_6_173_1
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e_1_2_6_3_2
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e_1_2_6_47_2
e_1_2_6_229_1
e_1_2_6_206_2
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e_1_2_6_52_2
e_1_2_6_75_2
e_1_2_6_90_2
e_1_2_6_119_2
e_1_2_6_172_1
e_1_2_6_111_1
e_1_2_6_157_1
e_1_2_6_195_1
e_1_2_6_134_2
e_1_2_6_160_1
e_1_2_6_217_1
e_1_2_6_37_3
e_1_2_6_14_2
e_1_2_6_37_2
e_1_2_6_98_2
e_1_2_6_63_2
e_1_2_6_86_2
e_1_2_6_168_3
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e_1_2_6_40_2
e_1_2_6_122_1
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e_1_2_6_220_1
e_1_2_6_4_2
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e_1_2_6_194_1
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e_1_2_6_133_2
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e_1_2_6_9_2
e_1_2_6_193_1
e_1_2_6_170_2
e_1_2_6_1_1
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e_1_2_6_227_1
e_1_2_6_204_2
e_1_2_6_45_2
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e_1_2_6_50_2
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e_1_2_6_117_2
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e_1_2_6_155_1
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e_1_2_6_35_2
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e_1_2_6_215_1
e_1_2_6_61_2
e_1_2_6_84_1
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e_1_2_6_93_2
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Snippet Bifunctional squaramides have emerged as powerful hydrogen‐bonding catalysts for promoting a wide array of useful asymmetric reactions, which provides...
Bifunctional squaramides have emerged as powerful hydrogen-bonding catalysts for promoting a wide array of useful asymmetric reactions, which provides...
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SubjectTerms asymmetric synthesis
Asymmetry
Bioactive compounds
Biological activity
Cascade chemical reactions
cascade reaction
Catalysts
Chemical bonds
Chemical reactions
Construction methods
hydrogen bond
Hydrogen bonding
Mannich reaction
Michael addition
organocatalysis squaramides
Title Squaramide‐Catalyzed Asymmetric Reactions
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Ftcr.201600140
https://www.ncbi.nlm.nih.gov/pubmed/28266131
https://www.proquest.com/docview/1950003042
https://www.proquest.com/docview/1875145187
Volume 17
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