New soluble porphyrazine derivatives containing electron-rich substituents

Hydroxypropylsulfanyl groups of metal-free and metallo-porphyrazines (M=2H, Mg, Cu, Zn, or Co) have been prepared by the esterification with a carboxylate such as 1-naphthoic acid. The symmetrically functionalized porphyrazines with eight ester units were soluble in common organic solvents such as C...

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Bibliographic Details
Published inJournal of coordination chemistry Vol. 66; no. 10; pp. 1720 - 1729
Main Author Gonca, Ergün
Format Journal Article
LanguageEnglish
Published Abingdon Routledge 01.05.2013
Taylor & Francis Ltd
Subjects
1-Naphthoic acid
Acetone
Cobalt
Esterification
Magnesium
Porphyrazine
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Summary:Hydroxypropylsulfanyl groups of metal-free and metallo-porphyrazines (M=2H, Mg, Cu, Zn, or Co) have been prepared by the esterification with a carboxylate such as 1-naphthoic acid. The symmetrically functionalized porphyrazines with eight ester units were soluble in common organic solvents such as CHCl 3 , CH 2 Cl 2 , tetrahydrofuran, acetone, and toluene and insoluble in water and n-hexane. The compounds have been characterized by FT-IR, UV-Vis, mass, 1 H, 13 C NMR, and elemental analysis.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
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ISSN:0095-8972
1029-0389
DOI:10.1080/00958972.2013.790018