Phytic acid-modified carboxymethyl cellulose hydrogel for uranium adsorption from aqueous solutions

• Published in: International journal of biological macromolecules Vol. 256; no. Pt 2; p. 128545
• Main Authors: Peng, Qihang, Jin, Tianxiang, Wang, Chongshi, Qian, Yong
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 01.01.2024
• Subjects: Adsorption; Carboxymethyl cellulose; Carboxymethylcellulose Sodium - chemistry; Hydrogels; Hydrogen-Ion Concentration; Ions; Kinetics; Phytic Acid; Uranium; Water - chemistry; Water Pollutants, Chemical - chemistry; Carboxymethyl cellulose; Uranium; Adsorption; Phytic acid
• ISSN: 0141-8130; 1879-0003
• DOI: 10.1016/j.ijbiomac.2023.128545

Phytic acid-modified carboxymethyl cellulose (CMC-PA) has been investigated as a promising adsorbent for the removal of uranium from aqueous solutions. The synthesis of CMC-PA involves the hydrogen bonding interaction between CMC and PA, resulting in the incorporation of PA groups onto the cellulose backbone. The hydrophilicity, reusability and adsorption capacity of the prepared CMC-PA hydrogel have improved with the increase of PA content. Moreover, the adsorption experiments were conducted by varying parameters such as pH, initial uranium concentration, and contact time. The results showed that CMC-PA exhibited excellent uranium adsorption performance, with a theoretical maximum adsorption capacity of 436 mg/g. In addition, the material exhibits excellent reusability, and the reusability improves with the increase of crosslinking density, indicating that the crosslinking structure of the polymer gel can effectively enhance the structural stability of the material. Furthermore, CMC-PA also exhibits high selective adsorption performance towards uranium ions in the presence of various competing ions. Its high adsorption capacity, reusability, and selectivity make it a promising candidate for high-performance uranium ion adsorbents.