Synthesis, Structure, and Property of One Nickel(II) Metal-Organic Frameworks Based on 4-Methylphthalic Acid and Imidazole-Containing Ligand
The title compound, {[Ni(L)(bbi)(H 2 O) 3 ]·(H 2 O)} n (I), where H 2 L = 4-methylphthalic acid and bbi = 1,1′-(1,4-butanediyl) bis(imidazole), crystallizes in the triclinic form with space group Pī and exhibits a 1D metal-organic chain. The Ni II cation is coordinated to four O atoms from one L 2-...
Saved in:
Published in | Inorganic and nano-metal chemistry Vol. 44; no. 7; pp. 946 - 950 |
---|---|
Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Abingdon
Taylor & Francis Group
09.08.2014
Taylor & Francis Ltd |
Subjects | |
Online Access | Get full text |
Cover
Loading…
Summary: | The title compound, {[Ni(L)(bbi)(H
2
O)
3
]·(H
2
O)}
n
(I), where H
2
L = 4-methylphthalic acid and bbi = 1,1′-(1,4-butanediyl) bis(imidazole), crystallizes in the triclinic form with space group Pī and exhibits a 1D metal-organic chain. The Ni
II
cation is coordinated to four O atoms from one L
2-
ligand and three coordinated water molecules, respectively, and two N atoms from two different bbi ligands, and these six donor atoms form an octahedral configuration. The bbi ligands connect the Ni
II
cations to form infinite chains, with the L ligands hanging on the two sides, which are further linked by rich hydrogen bonding system to generate a 3D supramolecular structure. |
---|---|
Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1553-3174 2470-1556 1553-3182 2470-1564 |
DOI: | 10.1080/15533174.2013.797445 |