Synthesis, Structure, and Property of One Nickel(II) Metal-Organic Frameworks Based on 4-Methylphthalic Acid and Imidazole-Containing Ligand

The title compound, {[Ni(L)(bbi)(H 2 O) 3 ]·(H 2 O)} n (I), where H 2 L = 4-methylphthalic acid and bbi = 1,1′-(1,4-butanediyl) bis(imidazole), crystallizes in the triclinic form with space group Pī and exhibits a 1D metal-organic chain. The Ni II cation is coordinated to four O atoms from one L 2-...

Full description

Saved in:
Bibliographic Details
Published inInorganic and nano-metal chemistry Vol. 44; no. 7; pp. 946 - 950
Main Authors Shan, WenWen, Ying, YiMei, Li, KaiHui, Mei, Chongzhen
Format Journal Article
LanguageEnglish
Published Abingdon Taylor & Francis Group 09.08.2014
Taylor & Francis Ltd
Subjects
3D supramolecular structure
Cations
Chains
Chemical bonds
coordination polymer
Crystallization
Hydrogen bonding
Imidazole
Ligands
Metal-organic frameworks
Nanostructure
Nickel compounds
Synthesis
Three dimensional
Online AccessGet full text

Cover

More Information
Summary:The title compound, {[Ni(L)(bbi)(H 2 O) 3 ]·(H 2 O)} n (I), where H 2 L = 4-methylphthalic acid and bbi = 1,1′-(1,4-butanediyl) bis(imidazole), crystallizes in the triclinic form with space group Pī and exhibits a 1D metal-organic chain. The Ni II cation is coordinated to four O atoms from one L 2- ligand and three coordinated water molecules, respectively, and two N atoms from two different bbi ligands, and these six donor atoms form an octahedral configuration. The bbi ligands connect the Ni II cations to form infinite chains, with the L ligands hanging on the two sides, which are further linked by rich hydrogen bonding system to generate a 3D supramolecular structure.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1553-3174
2470-1556
1553-3182
2470-1564
DOI:10.1080/15533174.2013.797445