Indirect electrochemical oxidation of aliphatic ketones mediated by the NaI–NaOH system:a facile way to unsaturated conjugated esters

Indirect electrochemical oxidation of aliphatic ketones in methanol in an undivided cell in the presence of sodium iodide–sodium hydroxide system leads to the corresponding unsaturated esters as a result of the electrochemically induced Favorskii rearrangement of the primarily formed α,α-diiodoketon...

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Published inElectrochimica acta Vol. 43; no. 8; pp. 973 - 976
Main Authors Barba, Fructuoso, Elinson, Mikhail N., Escudero, José, Guirado, Monica, Feducovich, Sergey K.
Format Journal Article
LanguageEnglish
Published Oxford Elsevier Ltd 01.01.1998
Elsevier
Subjects
aliphatic ketones
alkenecarboxylates
Favorskii rearrangement
indirect electrooxidation
mediator
indirect electrooxidation
Favorskii rearrangement
mediator
aliphatic ketones
alkenecarboxylates
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Summary:Indirect electrochemical oxidation of aliphatic ketones in methanol in an undivided cell in the presence of sodium iodide–sodium hydroxide system leads to the corresponding unsaturated esters as a result of the electrochemically induced Favorskii rearrangement of the primarily formed α,α-diiodoketones.
Bibliography:ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ISSN:0013-4686
1873-3859
DOI:10.1016/S0013-4686(97)00261-2