Redox activation of a B-H bond: a new route to metallaboratrane complexes

Oxidative activation of a B - H bond of a coordinated scorpionate ligand provides an unprecedented route to rhodaboratranes.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 22; pp. 2350 - 2352
Main Authors Blagg, Robin J., Charmant, Jonathan P. H., Connelly, Neil G., Haddow, Mairi F., Orpen, A. Guy
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2006
Subjects
Boranes - chemistry
Boron - chemistry
Chemistry
Chemistry, Multidisciplinary
Crystallography, X-Ray
Hydrogen - chemistry
Ligands
Models, Molecular
Molecular Structure
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Oxidation-Reduction
Physical Sciences
Rhodium - chemistry
Science & Technology
LIGANDS
MT
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Summary:Oxidative activation of a B - H bond of a coordinated scorpionate ligand provides an unprecedented route to rhodaboratranes.
ISSN:1359-7345
1364-548X
DOI:10.1039/b604954k