A non-thermal chemical synthesis of hydrophilic and amorphous cobalt oxide films for supercapacitor application

• Published in: Applied surface science Vol. 253; no. 8; pp. 3952 - 3956
• Main Authors: Kandalkar, Sunil G., Lokhande, C.D., Mane, R.S., Han, Sung-Hwan
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 15.02.2007; Elsevier Science
• Subjects: Cobalt oxide; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Condensed matter: structure, mechanical and thermal properties; Cross-disciplinary physics: materials science; rheology; Electrical resistivity; Exact sciences and technology; Non-thermal process; Physics; Raman shift; Cobalt oxide; Non-thermal process; Raman shift; Electrical resistivity; Electrical conductivity; Transition elements; Amorphous state; Chemical synthesis; Cobalt
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2006.08.026

Present work explored a room temperature, simple and low cost chemical route for the preparation of hydrophilic cobalt oxide films from alkaline cobalt chloride (CoCl 2:6H 2O) and double distilled water precursor solutions. As-deposited cobalt oxide films showed amorphous nature, which is one of the prime requirements for supercapacitor, as confirmed from X-ray diffraction studies. Changes in direct band gap energy and electrical resistivity of as-deposited cobalt oxide films were confirmed after annealing. Spherical grains of about 40–50 nm diameters were uniformly distributed over the substrate surface. Surface wettability studied in contact with liquid interface, showed hydrophilic nature as water contact angle was <90°. Finally, presence of cobalt–oxygen covalent bond was observed from Raman shift experiment.